臭氧氧化-循环喷淋法处理钨钼选矿废水

采用臭氧氧化-循环喷淋法去除钨钼选矿废水中COD,研究了pH值、臭氧流量、循环频率对COD去除效果的影响。结果表明: 废水COD去除率随pH值、臭氧流量、循环频率增大而增加,在pH值为10、臭氧流量3.0 L/min、循环频率4.0次/min条件下,氧化120 min后废水COD含量由131 mg/L降至11.5 mg/L,COD去除率达91.2%,满足《污水综合排放标准》(GB 8978-1996)一级标准。与O₂、NaClO处理废水COD的对比试验结果表明,循环喷淋法结合O₃表现出较好的COD去除效果。     

基于物联网的智能化窨井管理系统的设计

通信管道承载着户外传输网络,是通信网络的生命管道。管道规模伴随着城市化进程快速成倍增长,但管道管理还处于传统的依赖人工专项梳理、专项盯防的模式。随着智慧城市建设的加速推进,采用“物理加锁+物联网管理平台”的创新管理方式,结合物联网技术和大数据技术,实现对流程、人员、设备的全方位管理。     

Cross‐Linked Fluorinated Poly(Aryl Ether) (C‐FPAE) Films: Preparation Strategy,Performance Study,and Low Dielectric Applications

The production of low dielectric materials that can be used in high temperature environments is the primary aim of this work. A cross‐linked structure is introduced into fluorinated poly(aryl ether) (named as FPAE) with high molecular weight (M_w, 140 000 g mol^?1) and linear molecular structure using nucleophilic substitution reaction at the ortho‐position of decafluorobiphenyl monomer units in the FPAE molecular chain. The curing temperature and curing time are optimized and the final conditions for the cross‐linking reaction in this study are determined to be 300 °C for 1 h. Moreover, the dielectric constant and dielectric loss of the C‐FPAE film respectively are 2.67 and 0.006 at 1000 Hz when 1 wt% of crosslinking agent is added, and the cross‐linked fluorinated poly(aryl ether) film shows excellent thermal stability (T_d(5%), 495 °C), dimensional stability, hydrophobic properties, and high storage modulus in high temperature environments. Such novel low dielectric material with excellent performances has important application value in the aerospace and the integrated electronics field.     

Gui-A-Gra Attenuates Testicular Dysfunction in Varicocele-Induced Rats via Oxidative Stress,ER Stress and Mitochondrial Apoptosis Pathway

Gui-A-Gra, a commercial insect powder from Gryllus bimaculatus, is registered as an edible insect by the Korean food and drug administration. The aim of this study was to investigate the effect of Gui-A-Gra on testicular damage induced by experimental left varicocele in male Sprague Dawley rats. A total of 72 rats were randomly divided into the following six groups (12 rats in each group): a normal control group (CTR), a group administrated with Gui-A-Gra 1.63 gm/kg (G1.63), a group administrated with Gui-A-Gra 6.5 gm/kg (G6.5), a varicocele (VC)-induced control group (VC), a VC-induced group administrated with Gui-A-Gra 1.63 gm/kg (VC + G1.63), and a VC-induced group administrated with Gui-A-Gra 6.5 gm/kg (VC + G6.5). Rats were administrated 1.63 or 6.5 gm/kg Gui-A-Gra once daily for 42 days. Indicators of sperm parameters, histopathology, reproductive hormones, oxidative stress, endoplasmic reticulum (ER) stress, inflammation, and mitochondrial apoptosis were analyzed to evaluate effects of Gui-A-Gra on VC-induced testicular dysfunction. Gui-A-Gra administration to VC-induced rats significantly (p < 0.05) increased sperm count and sperm motility, Johnsen score, spermatogenic cell density, serum testosterone, testicular superoxide dismutase (SOD), glutathione peroxidase (GPx), catalase, GPx4, and steroidogenic acute regulatory protein (StAR) level. Moreover, pretreatment with Gui-A-Gra significantly (p < 0.05) decreased terminal deoxynucleotidyl transferase-mediated dUTP nick-end labeling (TUNEL) positive cells/tubules, serum luteinizing hormone (LH), serum follicle-stimulating hormone (FSH), testicular tumor necrosis factor-α (TNF-α), interleukin-6 (IL-6), malondialdehyde (MDA), reactive oxygen species (ROS)/reactive nitrogen species (RNS) level, glucose-regulated protein-78 (Grp-78), phosphorylated c-Jun-N-terminal kinase (p-JNK), phosphorylated inositol-requiring transmembrane kinase/endoribonuclease 1α (p-IRE1α), cleaved caspase-3, and BCL2 associated X protein: B-cell lymphoma 2 (Bax: Bcl2) ratio in VC rats. These results suggest that protective effects of Gui-A-Gra on VC-induced testicular injury might be due to its antioxidant, anti-inflammatory, and androgenic activities that might be mediated via crosstalk of oxidative stress, ER stress, and mitochondrial apoptosis pathway.     

纳米铁的绿色合成及其在环境中的应用研究进展

纳米铁（零价铁及铁氧化物）比表面积大、还原能力强、反应活性高，是一种良好的环境功能材料。传统的纳米铁合成方法中，物理方法对反应所需仪器设备要求较高，化学方法使用的还原剂具有毒性，绿色合成方法能够有效克服传统方法的不足之处。本文首先根据合成途径、纳米铁的类型介绍了利用植物和微生物对纳米零价铁（nZVI）及纳米铁氧化物（IONPs）进行绿色合成的方法，同时论述了制备的纳米铁所表现的特征（如形貌、尺寸、聚集倾向、等电位点）。随后总结了纳米铁通过不同反应机制（吸附、还原、催化氧化）去除环境有机、无机污染物（染料、芳香族化合物、硝酸盐、重金属）的应用。最后指出了纳米铁在绿色合成与实际应用过程中存在的挑战性问题及解决方法，以期为纳米铁今后的深入研究和大规模的工业生产应用提供参考依据。     

摩擦副表面气膜屏蔽微细电解加工微织构及摩擦性能分析

采用气膜屏蔽微细电解加工方法在金属平面副、圆柱副表面加工不同阵列形貌微织构。通过试验将该方法与微细电解加工的微织构尺寸精度、表面质量、摩擦性能进行对比，研究结果表明，气膜屏蔽微细电解加工的微织构相比微细电解加工方法加工的微织构平面副及圆柱副凹槽深径比分别提高了约45.6%和25.8%，改善了加工的定域性，提高了加工精度。进一步的摩擦磨损试验结果表明，相较于微细电解加工方法，气膜屏蔽微细电解加工出的平面副及圆柱副微凹槽的表面摩擦因数分别减小了13.6%与16.2%，表面摩擦性能得到了提高。     

不同结构石墨烯发声器的热声效率

为了研究不同石墨烯发声器结构对热声效率的影响,建立了石墨烯发声器的声压解析模型,对单层石墨烯发声器、多层石墨烯发声器以及镍铬基的泡沫石墨烯发声器的发声效率进行了理论与实验研究。首先,介绍了石墨烯发声器的工作原理,建立了石墨烯发声器的周期性温度变化模型和声压解析模型。然后,实验研究了单层石墨烯发声器、多层石墨烯发声器以及镍铬基的泡沫石墨烯发声器的热声效率。实验结果表明在14~25 kHz内,施加6 V交流电,测距为6 cm的条件下,单层、多层和泡沫石墨烯发声器的最高SPL分别为35.19,20.36和33.42 dB,SPL理论值最高约为37.45 dB。具有较低电阻,较低比热容,较高导热率的石墨烯发声器可以获得较高的热声效率和声压。     

一种基于多用户协同的网络定位性能评估方法

常见的网络定位技术主要有GNSS定位、基站定位、WiFi定位三种,每种定位技术都有其应用的场景和优缺点。现有的定位性能评估方法因涉及较专业的实验室设备,存在设备采购和维护成本高、场景覆盖较少等问题。本文提出了一种基于多用户协同的网络定位性能评估方法,该方法通过多用户手机协同机制采集大量高精度的GNSS基准位置评估基站或WiFi等粗精度网络定位性能,文章分析了该方法的实现流程,并通过试验场景和数据分析对比,最终给出了评价。     

基于优化遗传算法改进的小波网络预测锰系磷化膜的耐蚀性

针对小波网络训练速率较慢、结构不易确定等问题,结合实验选取的因素(包括输入参数和输出结果),通过仿真确定了小波网络的结构为3-7-1。接着,利用优化遗传算法对小波网络进行改进,修正其初始权值和因子。通过仿真证实了改进的小波网络具备更强的寻优能力和更快的收敛速率。最后,利用改进的小波网络预测锰系磷化膜的耐蚀性。结果表明:改进的小波网络可以更好地拟合样本数据,能够进行较准确的预测。     

Robustness analysis and distributed control of a networked system with time-varying delays

This paper is concerned with the robustness analysis and distributed output feedback control of a networked system with uncertain time-varying communication delays. This system consists of a collection of linear time-invariant subsystems that are spatially interconnected via an arbitrary directed network. Using a dissipation inequality that incorporates dynamic hard IQCs (integral quadratic constraints) for the delay uncertainties, we derive some sufficient robustness conditions in the form of coupled linear matrix inequalities, in which the coupled parts reflect the interconnection structure of the system. We then provide a procedure to construct a distributed controller to ensure the robust stability of the closed-loop system and to achieve a prescribed $\ell_2$-gain performance. The effectiveness of the proposed approach is demonstrated by some numerical examples.